Summary
Lists the versions in the workspace.
Discussion
You can specify the path to a connection file as an argument to the function or you can set the workspace environment to the connection file and call the ListVersions function without any arguments.
Note:
The arcpy.da.ListVersions function should not to be confused with the arcpy.ListVersions function which is used to return a list of version names the connected user has permission to use.
Syntax
ListVersions (sde_workspace)
| Parameter | Explanation | Data Type | 
| sde_workspace | An enterprise geodatabase workspace. | String | 
Code sample
Identify all versions modified within the last week.
import arcpy
import datetime
# Use datetime to establish current date/time
#
now = datetime.datetime.now()
sdeConnection = "Database Connections/toolboxDEFAULTVersion.sde"
# Compare lastModified property of each version to current date, and 
#  print version name if the version was modified in the last 7 days.
#
for version in arcpy.da.ListVersions(sdeConnection):
    if (now - version.lastModified).days < 7:
        print(version.name)Delete any versions belonging to a particular user and have no children.
import arcpy
sdeConnection = "Database Connections/toolboxDEFAULTVersion.sde"
for version in arcpy.da.ListVersions(sdeConnection):
    # Delete any versions owned by "RJones" that don't have any children
    #
    if version.name.split(".")[0] == "RJones" and not version.children:
        print("Deleting version {0}".format(version.name))
        arcpy.DeleteVersion_management(sdeConnection, version.name)